… We believe that the reaction of C 60 Cl 6 with thiols proceeds via a sequence of electron
transfer, chlorine anion elimination and RS − addition steps (a proposed mechanism is shown …

… With appropriate reagents, thiols react regioselectively with C 60 to form a fused … the
synthesis of novel chemically modified fullerenes from suitably functionalized pyrrolidino[3,4:1,2][60]…

… high yield synthetic methods to prepare new functional thiols. In this contribution, we show
that the synthesis of acetyl or benzoyl thioesters to introduce the thiol … , scalable preparation of …

… highly selective for thiols. Compound 5a was used as a representative electrophile (0.1 mM)
in reactions … , guanidine, and alkyne functional groups in addition to thiol, was mixed with an …

… reports on the thiol capture strategy. Init we describe a practical synthesis of 6-hydroxy-4-…
In the first step of Scheme I the reaction of a (sulfenylcarbomethoxy)-functionalized thiol with …

… The latter regenerates C 60 upon quenching of the reaction … functionalities such as hydroxyl,
thiol, ester, and carboxylic … Most functionalized organofullerenes described in this review …

… In connection with our extensive work on the design and synthesis of conjugated molecules,…
reactions. We also consider reactions that tolerate both free and protected thiol groups. …

… synthesis of α,ω-thiol-functionalized polystyrene telechelics by anionic polymerization upon
the reaction … current work demonstrates an extremely facile route to α,ω-thiol telechelics via …

… highly selective addition of thiols 15 to substituted olefins 16 under simple reaction conditions
with broad functional … thioether 17 in excellent yield (Scheme 6).29 This regioselective anti-…

… 5‘-thiol synthesis called for displacement of the 5‘-iodo group by thioacetate, with subsequent
release of the free thiol … to the thiol prevented us from obtaining consistently high yields. We …