金属有机硫化物框架用于制备高载量单原子Pt

L Yang, J Bai, W Liu, X Kan, G Lin, Y Zhang… - Science China …, 2022 - Springer
摘要原子级分散的贵金属位点在多相催化中具有广阔的应用前景. 然而当金属含量较高时极易
引起团聚, 因此其负载量通常限制在2 wt% 以下. 本研究中, 通过模拟金属酶的多中心金属硫簇 …

Boosting hydrogenation properties of Pt single-atom catalysts via tailoring the electronic structures by coordination number regulation

H Zhang, X Zhang, Q Sun, Q He, H Ji, X He - Chemical Engineering …, 2023 - Elsevier
Clarifying the relationship of single metal atom coordination structures and catalytic
properties is crucial for the fine-design of highly-efficient catalysts, but systematically …

New insight of pyrrole‐like nitrogen for boosting hydrogen evolution activity and stability of Pt single atoms

L Zhang, Q Wang, R Si, Z Song, X Lin, MN Banis… - Small, 2021 - Wiley Online Library
Single atomic Pt catalysts exhibit particularly high hydrogen evolution reaction (HER) activity
compared to conventional nanomaterial‐based catalysts. However, the enhanced …

Mesoporous sulfur-decorated Pt–Al2O3 for dehydrogenation of perhydro benzyltoluenes: activity-favorable adsorption of reaction species onto electron-deficient Pt …

Y Jo, TW Kim, J Oh, D Kim, YW Suh - Journal of Catalysis, 2022 - Elsevier
The addition of sulfur to supported Pt catalysts often regulates Pt defect sites causing side
reactions, where the interaction between Pt and sulfur depends on catalyst preparation …

Controllable coordination of a phosphotungstic acid-modified carbon matrix for anchoring Pt species with different sizes: from single atoms and subnanoclusters to …

J Li, Z Yan, L Bao, C Sun, S Pang - Catalysis Science & Technology, 2021 - pubs.rsc.org
Pt species with different sizes uniformly dispersed on a phosphotungstic acid (PTA) modified
carbon matrix (PTA-C) were controllably synthesized by manipulating the coordination …

Encapsulation of atomically dispersed Pt clusters in porous TiO 2 for semi-hydrogenation of phenylacetylene

H Wu, X Yang, S Zhao, L Zhai, G Wang… - Chemical …, 2022 - pubs.rsc.org
The synthesis of atomically dispersed metal clusters with strong interaction with the support
is attractive for the design of high-efficiency catalysts. Here, we report a multilayered catalyst …

Selective dissolution to synthesize densely populated Pt single atom catalyst

W Yang, X Zhao, Y Wang, R Wang, W Yang, Y Peng… - Nano Research, 2023 - Springer
Single atom catalysts (SACs) have become one of research focuses in heterogeneous
catalysis for their effective utilization of active metal atoms and unique properties in various …

Enhancing Stability of Mononuclear Pt Atoms Via Chloride-to-Bromide Ligand Exchange for Hydrosilylation Reaction

C Liang, K Liu, H Li, X Zhang, J Shen… - Available at SSRN … - papers.ssrn.com
Single atom catalysts (SACs) offer high atom efficiency with highly selective reaction
pathway. Various strategies have been developed to synthesize SACs, among which …

[引用][C] 金属有机硫化物框架用于制备高载量单原子Pt (英文)

杨丽君, 白静雯, 刘文刚, 阚晓楠, 林刚, 张媛媛…

[引用][C] Synthesis of atomic platinum with high loading on metal-organic sulfide

L Yang, J Bai, W Liu, X Kan… - SCIENCE …, 2022 - SCIENCE PRESS 16 …