4D–π–1A type β-substituted Zn II-porphyrins: ideal green sensitizers for building-integrated photovoltaics
Chemical Communications, 2016•pubs.rsc.org
Two novel green β-substituted ZnII-porphyrins, G1 and G2, based on a 4D–π–1A type
substitution pattern have been synthesized. Their enhanced push–pull character, by
reduction of H–L energy gaps, promotes broadening and red-shifting of absorption bands.
The effective synthetic pathway and the remarkable spectroscopic properties make G2 ideal
for BIPV application.
substitution pattern have been synthesized. Their enhanced push–pull character, by
reduction of H–L energy gaps, promotes broadening and red-shifting of absorption bands.
The effective synthetic pathway and the remarkable spectroscopic properties make G2 ideal
for BIPV application.
Two novel green β-substituted ZnII-porphyrins, G1 and G2, based on a 4D–π–1A type substitution pattern have been synthesized. Their enhanced push–pull character, by reduction of H–L energy gaps, promotes broadening and red-shifting of absorption bands. The effective synthetic pathway and the remarkable spectroscopic properties make G2 ideal for BIPV application.
The Royal Society of Chemistry