Synthesis, Modification, and Characterization of l-Lactide/2,2-[2-Pentene-1,5-diyl]trimethylene Carbonate Copolymers
This paper explores the copolymerization of l-lactide (l-LA) with 2,2-[2-pentene-1,5-diyl]trimethylene
carbonate ( c HTC). Since c HTC has a cyclohexene group, this provided a route for …
carbonate ( c HTC). Since c HTC has a cyclohexene group, this provided a route for …
Synthesis, Characterization, and Epoxidation of an Aliphatic Polycarbonate from 2,2-(2-Pentene-1,5-diyl)trimethylene Carbonate (cHTC) Ring-Opening …
… An outcome of this study was determining that the ZnEt 2 −H 2 O (1/0.5) catalyst for a
monomer/catalyst (M/C) molar ratio of 400 and a 2 h reaction time gave a product with M n = 276 …
monomer/catalyst (M/C) molar ratio of 400 and a 2 h reaction time gave a product with M n = 276 …
Reactivity of (2-alkenyl-3-pentene-1, 5-diyl) iron complexes: preparation of functionalized vinylcyclopropanes and cycloheptadienes
RK Pandey, L Wang, NJ Wallock… - The Journal of …, 2008 - ACS Publications
… (2-alkenyl-3-pentene-1,5-diyl)iron complexes can serve as organometallic scaffolds for the
preparation of a wide variety of structural motifs containing up to 5 contiguous stereocenters. …
preparation of a wide variety of structural motifs containing up to 5 contiguous stereocenters. …
Activation parameters for 1, 5-hydrogen transfer and intramolecular cycloaddition in a thermally generated cyclopentane-1, 3-diyl
TH Peterson, BK Carpenter - Journal of the American Chemical …, 1993 - ACS Publications
… in 1 was introduced to inhibit cyclopentene formation by 1,2-… if one uses a ring strainequal
to that for cyclopentene (5.9 kcal/mol) and a “Doering correction” 22 of 5.4 kcal/mol for the two …
to that for cyclopentene (5.9 kcal/mol) and a “Doering correction” 22 of 5.4 kcal/mol for the two …
Reactions of Substituted (2-Butene-1, 4-diyl) magnesium Complexes with Carboxylic Esters and Lactones: Formation of a Versatile Intermediate Capable of …
RD Rieke, MS Sell, H Xiong - Journal of the American Chemical …, 1995 - ACS Publications
… -íerí-butyl-líf-inden-2-olin 83% isolated yield, which resulted by reaction of (2,3-dimethyl-2butene-1,4-diyl)magnesium
with ethyl trimethylacetate at —78 C and quenched at —20 C with …
with ethyl trimethylacetate at —78 C and quenched at —20 C with …
… initiated thermal chemistry: Pseudopericylic reactions of (Z)-2-Acetoxy-3-pentene and reaction dynamics of exo, exo-5, 6-Dideuterio-2, 3-diaza [2.2. 1] bicyclohept-2 …
H Ji - 2010 - ttu-ir.tdl.org
… the pericyclic hydrocarbon retroene reaction of 1-pentene (5) and (B) in the planar,
pseudopericyclic βelimination of ethyl formate (3). (C, D) HOMO (in-plane) and HOMO-1 (out-ofplane) …
pseudopericyclic βelimination of ethyl formate (3). (C, D) HOMO (in-plane) and HOMO-1 (out-ofplane) …
Ring Opening of 1‐Methylcyclopropene and Cyclopropene: Matrix Infrared Spectroscopic Identification of 2‐Butene‐1, 3‐diyl and Propene‐1, 3‐diyl
G Maier, C Lautz, S Senger - Chemistry–A European Journal, 2000 - Wiley Online Library
… 2-Butene-1,3-diyl (11… 1 and Table 1, the experimental band positions are compared
with the calculated IR spectra of triplet trans-2butene-1,3-diyl (T-11 t) and triplet cis-2-butene-1,3-diyl …
with the calculated IR spectra of triplet trans-2butene-1,3-diyl (T-11 t) and triplet cis-2-butene-1,3-diyl …
Palladium (0)-catalyzed reaction of (Z)-2-butene-1, 4-diyl bis (methyl carbonate) and (Z)-2-butene-1, 4-diyl diacetate with bifunctional nitrogen nucleophiles
T Tsuda, T Kiyoi, T Saegusa - The Journal of Organic Chemistry, 1990 - ACS Publications
… (Z)-2-Butene-l,4-diyl diacetate (2) was distilled under nitrogen after drying over CaS04. (Z)-2-Butene-1,4-diylbis(methyl
carbonate) (1) was prepared by the reaction of (Z)-2-butene1,4-…
carbonate) (1) was prepared by the reaction of (Z)-2-butene1,4-…
… of Bridgehead-Methyl-Substituted Radical Cations Derived from Bicyclo [2.1. 0] pentanes and 2, 3-Diazabicyclo [2.2. 1] hept-2-enes through Photoinduced Electron …
W Adam, C Sahin, J Sendelbach, H Walter… - Journal of the …, 1994 - ACS Publications
Abstract: Cyclopentane-1, 3-diyl radical cations were generated from the 1-methyl-and 1, 4-dimethyl …
by a 1, 2-hydrogen shift to 3b,+, even at 80 K, and no trace of the more stable …
by a 1, 2-hydrogen shift to 3b,+, even at 80 K, and no trace of the more stable …
Photoreactions of decacarbonyl-dirhenium with branched derivatives of Allene
CG Kreiter, W Michels, G Heeb - Journal of organometallic chemistry, 1995 - Elsevier
… 2-en1,2-diyl complexes lose carbon monoxide and are transformed into octacacarbonyl-/x-B2:2-cumulene-dirhenium
[5… dimerization of two pentacarbonyl(3-~-4methyl-3-penten-2,3-diyl)…
[5… dimerization of two pentacarbonyl(3-~-4methyl-3-penten-2,3-diyl)…
相关搜索
- complex carbocycles 2 butene 1
- trimethylene carbonate copolymers 2 pentene 1
- aliphatic polycarbonate 2 pentene 1
- magnesium complexes 2 butene 1
- ring opening 2 butene 1
- functionalized vinylcyclopropanes 5 diyl
- 5 dithiahex 1 trideuterio 2
- exo 5 3 pentene
- spectroscopic identification 5 diyl
- 3 diyl 5 hydrogen transfer
- 3 diyl cyclohexane 1
- functionalized ketones 2 butene 1
- highly reactive magnesium 2 butene 1
- facile formation 2 butene 1
- direct synthesis 2 butene 1
- characterization of l lactide 5 diyl