A review of cation-ordered rock salt superstructure oxides

GC Mather, C Dussarrat, J Etourneau… - Journal of Materials …, 2000 - pubs.rsc.org
Journal of Materials Chemistry, 2000pubs.rsc.org
The types of structures formed when two or more cations occupy the sodium sites in the
NaCl unit cell in a non-random manner are reviewed with reference to the cation
arrangement in layers of close-packed octahedra and the cation arrangement in the NaCl
subcell. Factors influencing the stability of particular structure types, including bond valence
and radius ratios, are discussed.
The types of structures formed when two or more cations occupy the sodium sites in the NaCl unit cell in a non-random manner are reviewed with reference to the cation arrangement in layers of close-packed octahedra and the cation arrangement in the NaCl subcell. Factors influencing the stability of particular structure types, including bond valence and radius ratios, are discussed.
The Royal Society of Chemistry
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