Advances in interactive supported electrocatalysts for hydrogen and oxygen electrode reactions

NV Krstajic, LM Vracar, VR Radmilovic… - Surface Science, 2007 - Elsevier
Magneli phases [A. Magneli, Acta Chem. Scand. 13 (1959) 5] have been introduced as a
unique electron conductive and interactive support for electrocatalysis both in hydrogen
(HELR) and oxygen (OELR) electrode reactions in water electrolysis and Low Temperature
PEM Fuel Cells (LT PEM FC). The Strong Metal-Support Interaction (SMSI) that imposes the
former implies:(i) the hypo–hyper-d-interbonding effect and its catalytic consequences, and
(ii) the interactive primary oxide (M-OH) spillover from the hypo-d-oxide support as a …
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