… , allylic ethers and allylic … in allylic substitution reactions: the use of unactivated alcohols
minimizes the production of waste by-products and reaction steps; and allylic ethers and allylic …

In this review, we summarize the origin and advancements of iridium-catalyzed asymmetric
allylic substitution reactions during the past two decades. Since the first report in 1997, Ir-…

… copper-catalyzed conjugate additions and allylic substitution reactions (we can easily count
… the copper-catalyzed conjugate additions and allylic substitution reactions. (2) However, …

… Metal catalyzed allylic substitution is a cornerstone of organometallic and synthetic … -catalyzed
reaction are the formation of branched, chiral products from simple monosubstituted allylic …

… Since it was first reported in 1965,[1] the allylic substitution reaction has become a
powerful and widely used transformation for the construction of α- and β-substituted carbonyl …

… the desired substitution reaction. The use of palladium-catalyzed allylic alkylations,1·2
which allows use of the configurationally stable and easily handled allylic acetates, overcomes …

… , supporting their intermediacy in the catalytic reactions. On the basis of the structural data, a
… -catalyzed asymmetric allylic substitution reactions. Iridium-catalyzed allylic substitution has …

… The palladium-catalyzed asymmetric allylic substitution, … the Pd-catalyzed allylic substitution
reactions have used three … of the nucleophile to one of the allylic terminal carbon atoms. The …

… In summary, we have developed the first copper-catalyzed S N 2′-selective allylic substitution
reaction which utilizes readily accessible 1,1-diborylalkanes as the coupling partners. …

… alcohols; silver salts are readily available Lewis acids that had not previously been used
in direct intermolecular allylic substitution reactions using allylic alcohols.[8] The use of silver(I) …