Aromatic methoxylation and hydroxylation by organometallic high-valent nickel complexes
Herein we report the synthesis and reactivity of several organometallic NiIII complexes
stabilized by a modified tetradentate pyridinophane ligand containing one phenyl group. A
room temperature stable dicationic NiIII–disolvento complex was also isolated, and the
presence of two available cis coordination sites in this complex offers an opportunity to
probe the C-heteroatom bond formation reactivity of high-valent Ni centers. Interestingly, the
NiIII-dihydroxide and NiIII-dimethoxide species can be synthesized, and they undergo aryl …
stabilized by a modified tetradentate pyridinophane ligand containing one phenyl group. A
room temperature stable dicationic NiIII–disolvento complex was also isolated, and the
presence of two available cis coordination sites in this complex offers an opportunity to
probe the C-heteroatom bond formation reactivity of high-valent Ni centers. Interestingly, the
NiIII-dihydroxide and NiIII-dimethoxide species can be synthesized, and they undergo aryl …
[引用][C] Aromatic Methoxylation and Hydroxylation by Organometallic High-Valent Nickel Complexes
Z Wen - 2015
以上显示的是最相近的搜索结果。 查看全部搜索结果