Asmic: an exceptional building block for isocyanide alkylations
E Alwedi, JA Lujan-Montelongo, BR Pitta, A Chao… - Organic …, 2018 - ACS Publications
Organic letters, 2018•ACS Publications
Asmic addresses the long-standing challenge of alkylating isocyanides, providing access to
isocyanides with diverse substitution patterns. The o-anisylsulfanyl group serves a critical
dual role by facilitating deprotonation–alkylation and providing a latent nucleophilic site
through an unusual arylsulfanyl–lithium exchange.
isocyanides with diverse substitution patterns. The o-anisylsulfanyl group serves a critical
dual role by facilitating deprotonation–alkylation and providing a latent nucleophilic site
through an unusual arylsulfanyl–lithium exchange.
Asmic addresses the long-standing challenge of alkylating isocyanides, providing access to isocyanides with diverse substitution patterns. The o-anisylsulfanyl group serves a critical dual role by facilitating deprotonation–alkylation and providing a latent nucleophilic site through an unusual arylsulfanyl–lithium exchange.
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