Atranones: Novel diterpenoids from the toxigenic mold Stachybotrys atra

SF Hinkley, J Jiang, EP Mazzola, BB Jarvis - Tetrahedron Letters, 1999 - Elsevier
atra cultures, we have isolated a set of novel compounds related in structure to the
dolabellane diterpene ring system [9], but which is further elaborated by a four-carbon
fragment with an unusual fused enol lactone system. … 2), a structural unit unique to the
atranones. With the structure of atranone C secure, we were able to assign with confidence
the structures of atranones A and B [12] based on the 1H and 13C NMR data, including
NOESY correlations (Table 1). The double bond isomeric …
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