Chain transfer to aluminium in MAO-activated metallocene-catalyzed polymerization reactions
E Quintanilla, F di Lena, P Chen - Chemical communications, 2006 - pubs.rsc.org
E Quintanilla, F di Lena, P Chen
Chemical communications, 2006•pubs.rsc.orgChemical trapping of metal-bound oligomeric chains during the MAO-activated, metallocene-
catalyzed polymerization of ethylene identify the two observed chain-bearing species to be
alkylzirconocenium species and higher alkyl aluminiums, consistent with a proposed
mechanism.
catalyzed polymerization of ethylene identify the two observed chain-bearing species to be
alkylzirconocenium species and higher alkyl aluminiums, consistent with a proposed
mechanism.
Chemical trapping of metal-bound oligomeric chains during the MAO-activated, metallocene-catalyzed polymerization of ethylene identify the two observed chain-bearing species to be alkylzirconocenium species and higher alkyl aluminiums, consistent with a proposed mechanism.
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