Charge-regulated spontaneous, reversible self-assembly of the carboxylic acid-functionalized hydrophilic fullerene macroanions in dilute solution
Fullerene molecule covalently functionalized with 12 carboxylic acid groups on its periphery
was synthesized, and its solution behavior was explored. The functionalized fullerene
molecules behave as hydrophilic macroions in polar solvents by showing strong attractions
with each other mediated from their counterions and consequently self-assembling into
single-layer, hollow, spherical blackberry-type structures in solvents with moderate polarity.
The fullerene molecules are not touching with each other in the assemblies, and the …
was synthesized, and its solution behavior was explored. The functionalized fullerene
molecules behave as hydrophilic macroions in polar solvents by showing strong attractions
with each other mediated from their counterions and consequently self-assembling into
single-layer, hollow, spherical blackberry-type structures in solvents with moderate polarity.
The fullerene molecules are not touching with each other in the assemblies, and the …
[引用][C] Charge-Regulated Spontaneous, Reversible Self-Assembly of the Carboxylic Acid-Functionalized Hydrophilic Fullerene Macroanions in Dilute Solution
Y Panchao, L Zhiwei, W Jiayingzi, H Chih-Hao… - 2015
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