Chiral metal–organic frameworks with tunable open channels as single-site asymmetric cyclopropanation catalysts
A pair of interpenetrated and non-interpenetrated chiral metal–organic frameworks with the
same catalytic sites but different open channel sizes catalysed asymmetric cyclopropanation
of substituted terminal alkenes with excellent diastereoselectivities (up to 9.6) and
enantioselectivities (up to> 99%).
same catalytic sites but different open channel sizes catalysed asymmetric cyclopropanation
of substituted terminal alkenes with excellent diastereoselectivities (up to 9.6) and
enantioselectivities (up to> 99%).
A pair of interpenetrated and non-interpenetrated chiral metal–organic frameworks with the same catalytic sites but different open channel sizes catalysed asymmetric cyclopropanation of substituted terminal alkenes with excellent diastereoselectivities (up to 9.6) and enantioselectivities (up to >99%).
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