We proposed and demonstrated a kinetically interlocking multiple-units supramolecular polymerization strategy. Through rationally designed multiple-units monomers, the degree of polymerization (X_w) detected was more than 50 with a polydispersity index of ∼1.4. The prepared polymers were stable when diluted to 20 μM or lower concentrations. By introducing the cooperative effects of multiunit interactions into a traditional condensation polymerization model, we found that the relationship between the concentration and the X_w was heavily influenced by the unit number involved in the kinetic interlocking. Factors that influenced the X_w and their distributions were studied systematically, and all the results matched the theoretical predictions excellently. This strategy provides novel insight into supramolecular polymerization and offers a simple but effective way to improve positive correlation of the reversibility and stability of supramolecular interactions in polymer assembly.