Creating Tunable Mesoporosity by Temperature‐Driven Localized Crystallite Agglomeration
A new synthetic approach for tunable mesoporous metal–organic frameworks (MeMs) is
developed. In this approach, mesopores are created in the process of heat conversion of
highly mosaic metal–organic framework (MOF) crystals with non‐interpenetrated low‐
density nanocrystallites into MOF crystals with two‐fold interpenetrated high‐density
nanocrystallites. The two‐fold interpenetration reduces the volume of the nanocrystallites in
the mosaic crystal, and the accompanying localized agglomeration of the nanocrystallites …
developed. In this approach, mesopores are created in the process of heat conversion of
highly mosaic metal–organic framework (MOF) crystals with non‐interpenetrated low‐
density nanocrystallites into MOF crystals with two‐fold interpenetrated high‐density
nanocrystallites. The two‐fold interpenetration reduces the volume of the nanocrystallites in
the mosaic crystal, and the accompanying localized agglomeration of the nanocrystallites …
[引用][C] Creating Tunable Mesoporosity by Temperature‐Driven Localized Crystallite Agglomeration (Small 7/2022)
In article number 2107006, Chae Un Kim, Ja-Hyoung Ryu, Myoung Soo Lah, and co-
workers synthesize a tunable mesoporous metal-organic framework that can be used for
enzymatic immobilization through heat treatment of highly mosaic crystals with low-density
crystallites through localized agglomeration of volume-reduced crystallites.
workers synthesize a tunable mesoporous metal-organic framework that can be used for
enzymatic immobilization through heat treatment of highly mosaic crystals with low-density
crystallites through localized agglomeration of volume-reduced crystallites.
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