Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes–fast phosphorescence or TADF?
J Nitsch, F Lacemon, A Lorbach, A Eichhorn… - Chemical …, 2016 - pubs.rsc.org
Chemical Communications, 2016•pubs.rsc.org
This case study on a series of monomeric, dimeric and polymeric CuI chlorido NHC–picolyl
complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast
(reverse) intersystem-crossing T1↔ S1 and T1→ S0, and therefore can serve as a design
motif for the construction of highly efficient CuI-based TADF or T1 emitters.
complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast
(reverse) intersystem-crossing T1↔ S1 and T1→ S0, and therefore can serve as a design
motif for the construction of highly efficient CuI-based TADF or T1 emitters.
This case study on a series of monomeric, dimeric and polymeric CuI chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T1 ↔ S1 and T1 → S0, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T1 emitters.
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