Detection and Identification of the Keto-Hydroperoxide (HOOCH2OCHO) and Other Intermediates during Low-Temperature Oxidation of Dimethyl Ether
K Moshammer, AW Jasper… - The Journal of …, 2015 - ACS Publications
In this paper we report the detection and identification of the keto-hydroperoxide
(hydroperoxymethyl formate, HPMF, HOOCH2OCHO) and other partially oxidized
intermediate species arising from the low-temperature (540 K) oxidation of dimethyl ether
(DME). These observations were made possible by coupling a jet-stirred reactor with
molecular-beam sampling capabilities, operated near atmospheric pressure, to a reflectron
time-of-flight mass spectrometer that employs single-photon ionization via tunable …
(hydroperoxymethyl formate, HPMF, HOOCH2OCHO) and other partially oxidized
intermediate species arising from the low-temperature (540 K) oxidation of dimethyl ether
(DME). These observations were made possible by coupling a jet-stirred reactor with
molecular-beam sampling capabilities, operated near atmospheric pressure, to a reflectron
time-of-flight mass spectrometer that employs single-photon ionization via tunable …
[PDF][PDF] Detection and Identification of the Keto-Hydroperoxide (HOOCH2OCHO) and other
In this paper we report the detection and identification of the keto-hydroperoxide
(hydroperoxymethyl formate, HPMF, HOOCH2OCHO) and other partially oxidized
intermediate species arising from the low-temperature (540 K) oxidation of dimethyl ether
(DME). These observations were made possible by coupling a jet-stirred reactor with
molecular-beam sampling capabilities, operated near atmospheric pressure, to a reflectron
time-of-flight mass spectrometer that employs single-photon ionization via tunable …
(hydroperoxymethyl formate, HPMF, HOOCH2OCHO) and other partially oxidized
intermediate species arising from the low-temperature (540 K) oxidation of dimethyl ether
(DME). These observations were made possible by coupling a jet-stirred reactor with
molecular-beam sampling capabilities, operated near atmospheric pressure, to a reflectron
time-of-flight mass spectrometer that employs single-photon ionization via tunable …