Dynamic behavior in diplatinum metalloreceptors
AJ Baer, BD Koivisto, AP Côté, NJ Taylor… - Inorganic …, 2002 - ACS Publications
Inorganic chemistry, 2002•ACS Publications
… Diplatinum metalloreceptors anti-4a and anti-4b exhibit dynamic behavior in solution that
is modified by anion binding. An X-ray crystal structure determination of anti-4a supports its
proposed solution structure. … Herein we apply this strategy to the synthesis of a new
series of dynamic diplatinum metallomacrocycles and present their NMR behavior and host−guest
chemistry based on interactions with the secondary coordination sphere of the
metalloreceptors. … We are currently exploring the dynamic behavior of the Pt …
is modified by anion binding. An X-ray crystal structure determination of anti-4a supports its
proposed solution structure. … Herein we apply this strategy to the synthesis of a new
series of dynamic diplatinum metallomacrocycles and present their NMR behavior and host−guest
chemistry based on interactions with the secondary coordination sphere of the
metalloreceptors. … We are currently exploring the dynamic behavior of the Pt …
Diplatinum metalloreceptors anti-4a and anti-4b exhibit dynamic behavior in solution that is modified by anion binding. An X-ray crystal structure determination of anti-4a supports its proposed solution structure.
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