Effect of chain rigidity on the decoupling of ion motion from segmental relaxation in polymerized ionic liquids: Ambient and elevated pressure studies
Conductivity in polymer electrolytes has been generally discussed with the assumption that
the segmental motions control charge transport. However, much less attention has been
paid to the mechanism of ion conductivity where the motions of ions are less dependent
(decoupled) on segmental dynamics. This phenomenon is observed in ionic materials as
they approach their glass transition temperature and becomes essential for design and
development of highly conducting solid polymer electrolytes. In this paper, we study the …
the segmental motions control charge transport. However, much less attention has been
paid to the mechanism of ion conductivity where the motions of ions are less dependent
(decoupled) on segmental dynamics. This phenomenon is observed in ionic materials as
they approach their glass transition temperature and becomes essential for design and
development of highly conducting solid polymer electrolytes. In this paper, we study the …
[引用][C] Effect of Chain Rigidity on the Decoupling of Ion Motion from Segmental Relaxation in Polymerized Ionic Liquids: Ambient and Elevated Pressure Studies
W Zaneta, F Hongbo, F Yao, C Shiwang, C Bobby… - 2017