Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate
Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of
(S)-(−)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc
incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures
of guest molecules, extending chiral recognition in inorganic materials to three-dimensional
crystal growth.
(S)-(−)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc
incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures
of guest molecules, extending chiral recognition in inorganic materials to three-dimensional
crystal growth.
Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of (S)-(−)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures of guest molecules, extending chiral recognition in inorganic materials to three-dimensional crystal growth.
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