Energy transfer and excited state lifetime of some anthracene laser dyes

R Ghazy, SA Zim, M Shaheen, F El-Mekawey - Optics & Laser Technology, 2004 - Elsevier
R Ghazy, SA Zim, M Shaheen, F El-Mekawey
Optics & Laser Technology, 2004Elsevier
The lifetimes of some anthrathene derivatives in different solvents have been determined
using the phase modulation method. The lifetime of 10-phenyl-2-methyl-9-
acetoxyanthracene and 10-(4-acetoxyphenyl)-2-methyl-9-acetoxyanthracene were found to
equal 11 and 11 ns in methanol, respectively. Energy transfer from 10-phenyl-2-methyl-9-
acetoxyanthracene and 10-(4-acetoxyphenyl)-2-methyl-9-acetoxyanthracene to rhodamine
B and rhodamine 110 in different solvents has been studied by using steady-state emission …
The lifetimes of some anthrathene derivatives in different solvents have been determined using the phase modulation method. The lifetime of 10-phenyl-2-methyl-9-acetoxyanthracene and 10-(4-acetoxyphenyl)-2-methyl-9-acetoxyanthracene were found to equal 11 and 11 ns in methanol, respectively. Energy transfer from 10-phenyl-2-methyl-9-acetoxyanthracene and 10-(4-acetoxyphenyl)-2-methyl-9-acetoxyanthracene to rhodamine B and rhodamine 110 in different solvents has been studied by using steady-state emission measurements. The large values of the critical transfer distance R0 and the rate constant of energy transfer kET suggest that the mechanism is long-range dipole–dipole energy transfer as described by Förster.
Elsevier
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