[HTML][HTML] Ethylene oxide monitor with part-per-trillion precision for in situ measurements
TI Yacovitch, C Dyroff, JR Roscioli… - Atmospheric …, 2023 - amt.copernicus.org
Atmospheric Measurement Techniques, 2023•amt.copernicus.org
An Aerodyne tunable infrared laser direct absorption spectrometer with a multipass cell with
a 413 m pathlength for the detection of ethylene oxide (EtO) is presented (TILDAS-FD-EtO).
This monitor achieves precisions of< 75 ppt or< 0.075 ppb s-1 and< 20 ppt in 100 s (1 σ). We
demonstrate precisions averaging down to 4 ppt h-1 (1 σ precision) when operated with
frequent humidity-matched zeroes. A months-long record of 2022 ambient concentrations at
a site in the eastern United States is presented. Average ambient EtO concentration is on the …
a 413 m pathlength for the detection of ethylene oxide (EtO) is presented (TILDAS-FD-EtO).
This monitor achieves precisions of< 75 ppt or< 0.075 ppb s-1 and< 20 ppt in 100 s (1 σ). We
demonstrate precisions averaging down to 4 ppt h-1 (1 σ precision) when operated with
frequent humidity-matched zeroes. A months-long record of 2022 ambient concentrations at
a site in the eastern United States is presented. Average ambient EtO concentration is on the …
Abstract
An Aerodyne tunable infrared laser direct absorption spectrometer with a multipass cell with a 413 m pathlength for the detection of ethylene oxide (EtO) is presented (TILDAS-FD-EtO). This monitor achieves precisions of ppt or ppb s and ppt in 100 s (1). We demonstrate precisions averaging down to 4 ppt h (1 precision) when operated with frequent humidity-matched zeroes. A months-long record of 2022 ambient concentrations at a site in the eastern United States is presented. Average ambient EtO concentration is on the order of 18 ppt (22 ppt standard deviation, SD). Enhancement events of EtO lasting a few hours are observed, with peaks as high as 600 ppt. Back-trajectory simulations suggest an EtO source nearly 35 km away. This source along with another are confirmed as emitters through mobile near-source measurements, with downwind concentrations in the 0.5 to 700 ppb range depending on source identity and distance downwind.
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