First neodymium (III) alkyl-carbene complex based on bis (iminophosphoranyl) ligands
A Buchard, A Auffrant, L Ricard, XF Le Goff… - Dalton …, 2009 - pubs.rsc.org
Dalton Transactions, 2009•pubs.rsc.org
Serendipitous deprotonation of bis (iminophosphoranyl) methanide Nd (III) complexes
afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally
similar methanide and methandiide fragments, this complex features, as evidenced by X-ray
crystallographic analysis, Nd–C single and multiple bonds.
afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally
similar methanide and methandiide fragments, this complex features, as evidenced by X-ray
crystallographic analysis, Nd–C single and multiple bonds.
Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(III) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd–C single and multiple bonds.
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