First stereoselective syntheses of (−)-siphonodiol and (−)-tetrahydrosiphonodiol, bioactive polyacetylenes from marine sponges
S López, F Fernández-Trillo, P Midón… - The Journal of …, 2005 - ACS Publications
S López, F Fernández-Trillo, P Midón, L Castedo, C Saá
The Journal of Organic Chemistry, 2005•ACS PublicationsThe first stereoselective total syntheses of the bioactive marine polyacetylenes (−)-
siphonodiol and (−)-tetrahydrosiphonodiol were achieved using highly convergent
approaches based on optimized Cadiot− Chodkiewicz and sequential Sonogashira cross-
coupling reactions.
siphonodiol and (−)-tetrahydrosiphonodiol were achieved using highly convergent
approaches based on optimized Cadiot− Chodkiewicz and sequential Sonogashira cross-
coupling reactions.
The first stereoselective total syntheses of the bioactive marine polyacetylenes (−)-siphonodiol and (−)-tetrahydrosiphonodiol were achieved using highly convergent approaches based on optimized Cadiot−Chodkiewicz and sequential Sonogashira cross-coupling reactions.
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