… to produce novel fluorinated commodities. Here, we review the fluorinase biotechnology
and fluorine biocatalysts that incorporate fluorine motifs to generate fluorinated molecules, and …

Fluorinases, the only enzymes known to catalyze the transfer of fluorine to an organic molecule,
are essential catalysts for the biological synthesis of valuable organofluorines. However, …

… interesting building-block for biocatalysis as it can be activated … These six enzymes are key
to developing fluorine biocatalysis; … platform for biohalogenation via whole-cell biocatalysis …

… that introduction of fluorinated amino acids constitute an … stable biocatalysts for industrial
applications. Despite these being preliminary results and none of these fluorinated biocatalysts …

… Fluorinated amino acids serve as an entry point for establishing new-to-Nature chemistries
… enzymatic synthesis of fluorinated alanine enantiomers to expand fluorine biocatalysis. The …

… Biocatalytic oxidation and reduction defluorination by micro-organisms containing organic
fluorine compounds have been reviewed to analyze their ability to handle such specific …

… oxygenation at C3 concomitant with a carbon–fluorine bond cleavage to yield DOPA and
fluoride. … Thus, this finding reveals a significant potential of biocatalysis in C–H/C–X bond (X = …

… As such, reductive aminase provides a sustainable and highly economical biocatalysis
toolbox, which can synthesize fluorinated chiral amines and fluorinated chiral alcohols from …

… Biocatalysis offers a complementary approach with the potential for exceptional selectivity
… , interfacing biocatalysis with fluorine chemistry must contend with the rarity of fluorine in the …

… In this review, we present the discovery of fluorinated natural … of fluorine-containing
compounds in recent years. It is hoped that this review will help to promote the field of biocatalytic …