Gold (I)-catalyzed activation of alkynes for the construction of molecular complexity
R Dorel, AM Echavarren - Chemical reviews, 2015 - ACS Publications
Chemical reviews, 2015•ACS Publications
For centuries, gold had been considered a precious, purely decorative inert metal. It was not
until 1986 that Ito and Hayashi described the first application of gold (I) in homogeneous
catalysis. 1 More than one decade later, the first examples of gold (I) activation of alkynes
were reported by Teles 2 and Tanaka, 3 revealing the potential of gold (I) in organic
synthesis. Now, gold (I) complexes are the most effective catalysts for the electrophilic
activation of alkynes under homogeneous conditions, and a broad range of versatile
until 1986 that Ito and Hayashi described the first application of gold (I) in homogeneous
catalysis. 1 More than one decade later, the first examples of gold (I) activation of alkynes
were reported by Teles 2 and Tanaka, 3 revealing the potential of gold (I) in organic
synthesis. Now, gold (I) complexes are the most effective catalysts for the electrophilic
activation of alkynes under homogeneous conditions, and a broad range of versatile
For centuries, gold had been considered a precious, purely decorative inert metal. It was not until 1986 that Ito and Hayashi described the first application of gold (I) in homogeneous catalysis. 1 More than one decade later, the first examples of gold (I) activation of alkynes were reported by Teles 2 and Tanaka, 3 revealing the potential of gold (I) in organic synthesis. Now, gold (I) complexes are the most effective catalysts for the electrophilic activation of alkynes under homogeneous conditions, and a broad range of versatile
ACS Publications以上显示的是最相近的搜索结果。 查看全部搜索结果