High field magnetometry with hyperpolarized nuclear spins
O Sahin, E de Leon Sanchez, S Conti… - Nature …, 2022 - nature.com
O Sahin, E de Leon Sanchez, S Conti, A Akkiraju, P Reshetikhin, E Druga, A Aggarwal…
Nature communications, 2022•nature.comQuantum sensors have attracted broad interest in the quest towards sub-micronscale NMR
spectroscopy. Such sensors predominantly operate at low magnetic fields. Instead, however,
for high resolution spectroscopy, the high-field regime is naturally advantageous because it
allows high absolute chemical shift discrimination. Here we demonstrate a high-field spin
magnetometer constructed from an ensemble of hyperpolarized 13C nuclear spins in
diamond. They are initialized by Nitrogen Vacancy (NV) centers and protected along a …
spectroscopy. Such sensors predominantly operate at low magnetic fields. Instead, however,
for high resolution spectroscopy, the high-field regime is naturally advantageous because it
allows high absolute chemical shift discrimination. Here we demonstrate a high-field spin
magnetometer constructed from an ensemble of hyperpolarized 13C nuclear spins in
diamond. They are initialized by Nitrogen Vacancy (NV) centers and protected along a …
Abstract
Quantum sensors have attracted broad interest in the quest towards sub-micronscale NMR spectroscopy. Such sensors predominantly operate at low magnetic fields. Instead, however, for high resolution spectroscopy, the high-field regime is naturally advantageous because it allows high absolute chemical shift discrimination. Here we demonstrate a high-field spin magnetometer constructed from an ensemble of hyperpolarized 13C nuclear spins in diamond. They are initialized by Nitrogen Vacancy (NV) centers and protected along a transverse Bloch sphere axis for minute-long periods. When exposed to a time-varying (AC) magnetic field, they undergo secondary precessions that carry an imprint of its frequency and amplitude. For quantum sensing at 7T, we demonstrate detection bandwidth up to 7 kHz, a spectral resolution < 100mHz, and single-shot sensitivity of 410pT. This work anticipates opportunities for microscale NMR chemical sensors constructed from hyperpolarized nanodiamonds and suggests applications of dynamic nuclear polarization (DNP) in quantum sensing.
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