High-Yielding and Divergent Paradigm for the Synthesis of D2h-Symmetric Octakis-Substituted Pentiptycenequinones
GS Vadehra, X Jiang, JJ Dotson, GM Chu… - Organic …, 2017 - ACS Publications
With a rigid fused polyaromatic framework and a well-defined, highly symmetric molecular
geometry, pentiptycenes are appealing building blocks for a variety of materials
applications. Unfortunately, their use has been limited by the lengthy syntheses of their
functionalized derivatives. This communication describes a highly efficient, brief, divergent
paradigm for the preparation of octakis-substituted pentiptycene derivatives that starts with
the preparation of an octakis (bromo) compound, which can be used as a Pd (0)-catalyzed …
geometry, pentiptycenes are appealing building blocks for a variety of materials
applications. Unfortunately, their use has been limited by the lengthy syntheses of their
functionalized derivatives. This communication describes a highly efficient, brief, divergent
paradigm for the preparation of octakis-substituted pentiptycene derivatives that starts with
the preparation of an octakis (bromo) compound, which can be used as a Pd (0)-catalyzed …
[引用][C] High-Yielding and Divergent Paradigm for the Synthesis of D2h-Symmetric Octakis-Substituted Pentiptycenequinones
J Xing - 2017