Highly selective reactions of C 60 Cl 6 with thiols for the synthesis of functionalized [60] fullerene derivatives

EA Khakina, AA Yurkova, AS Peregudov… - Chemical …, 2012 - pubs.rsc.org
EA Khakina, AA Yurkova, AS Peregudov, SI Troyanov, VV Trush, AI Vovk, AV Mumyatov…
Chemical communications, 2012pubs.rsc.org
Chlorofullerene C60Cl6 undergoes highly selective reactions with thiols forming compounds
C60 [SR] 5H with high yields. These reactions open up straightforward synthetic routes to
many functionalized fullerene derivatives, eg water-soluble compounds showing interesting
biological activities.
Chlorofullerene C60Cl6 undergoes highly selective reactions with thiols forming compounds C60[SR]5H with high yields. These reactions open up straightforward synthetic routes to many functionalized fullerene derivatives, e.g. water-soluble compounds showing interesting biological activities.
The Royal Society of Chemistry
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