Hydrated electrons at the water/air interface
… water/air interface (the limit of infinite size) and show that, under ambient conditions, e − (aq)
is fully hydrated … pulse centered at 250 nm to eject an electron from I − ions adsorbed at the …
is fully hydrated … pulse centered at 250 nm to eject an electron from I − ions adsorbed at the …
Spectroscopy and dynamics of the hydrated electron at the water/air interface
CJC Jordan, MP Coons, JM Herbert… - nature …, 2024 - nature.com
… of a partially hydrated electron with most of its electron distribution … water/air interface suggests
a partially hydrated electron 21 , … for e – (aq) buried in the interface 22,23 . The theoretical …
a partially hydrated electron 21 , … for e – (aq) buried in the interface 22,23 . The theoretical …
Hydrated interfacial ions and electrons
B Abel - Annual review of physical chemistry, 2013 - annualreviews.org
… The features of the surface/interface hydrated electron have been discussed recently in terms
of a high Rydberg state of water squeezed out of the tight hydrogen bond network of water …
of a high Rydberg state of water squeezed out of the tight hydrogen bond network of water …
Excess electron relaxation dynamics at water/air interfaces
… the fully hydrated electron the quasidegeneracy of the three p -type excited states remains
on the water/air interface. The optical absorption spectrum for the surface state electron based …
on the water/air interface. The optical absorption spectrum for the surface state electron based …
Electronic states at the water/air interface
J Rodriguez, D Laria - The Journal of Physical Chemistry B, 2005 - ACS Publications
Using combined path integral−molecular dynamics simulation techniques, we analyze
electronic solvation at the water/air interface. Superficial electrons present a considerable extent …
electronic solvation at the water/air interface. Superficial electrons present a considerable extent …
Free energies of cavity and noncavity hydrated electrons near the instantaneous air/water interface
JR Casey, BJ Schwartz, WJ Glover - The journal of physical …, 2016 - ACS Publications
… volume of solvation for the hydrated electron, in contrast with both … bulk hydrated electron,
there has also been recent interest in the nature of hydrated electrons at the air/water interface. …
there has also been recent interest in the nature of hydrated electrons at the air/water interface. …
Charge transfer to solvent dynamics at the ambient water/air interface
PJ Nowakowski, DA Woods… - The Journal of Physical …, 2016 - ACS Publications
… pair with iodine and a free hydrated electron at the water/air interface. Our results suggest
that the hydrated electron is fully solvated in a region of reduced water density at the interface. …
that the hydrated electron is fully solvated in a region of reduced water density at the interface. …
The hydrated electron
JM Herbert, MP Coons - Annual review of physical chemistry, 2017 - annualreviews.org
… relative to that of a surfactant-free interface, but the signal changes significantly when the …
hydrated electron might reside 1–2 nm into solvent (122), near enough to the interface to lift …
hydrated electron might reside 1–2 nm into solvent (122), near enough to the interface to lift …
[HTML][HTML] Probing photochemical dynamics using electronic vs vibrational sum-frequency spectroscopy: The case of the hydrated electron at the water/air interface
FG Pritchard, CJC Jordan, JRR Verlet - The Journal of chemical …, 2024 - pubs.aip.org
… water/air interface for a hydrated electron formed by two-photon excitation of water (a), the
hydrated electron … Schematics of the electron distribution at the water/air interface are shown …
hydrated electron … Schematics of the electron distribution at the water/air interface are shown …
Nature of excess hydrated proton at the water–air interface
… We have characterized the nature of the hydrated proton adsorbed at the water–air interface.
… proton of ∼1.3 kcal/mol at the water–air interface is substantially larger than 0.6 kcal/mol (k …
… proton of ∼1.3 kcal/mol at the water–air interface is substantially larger than 0.6 kcal/mol (k …