… The main goals of this work were i) to explore alternative hypervalent iodine(III)-based …
transfer reactions are likely to take place from the hypervalent iodine(III)-based initiator PhIX2 …

In modern organic chemistry, hypervalent (HV) iodine (III) compounds are frequently used
as oxidizing agents but application of λ 3-iodanes in polymer and material chemistry is still …

… for the application of the hypervalent iodine compounds as … this iniferter effect and its spectral
selectivity, new possibilities for an application of both the 8-I-2 or 10-I-3 hypervalent iodine …

… with chain transfer reaction and iniferter quasi-living polymerization. In addition … hypervalent
iodine bond are the probable reason for the deviation of this polymerization from the iniferter …

… The discovery of controlled radical polymerization goes back to the invention of iniferters by
… for the fluorinated monomers,27 hypervalent iodide carboxylate-mediated controlled radical …

… Photo-mediated radical polymerization of polymerizable “iniferter” monomers [71,104,105,106,107]
is also discussed in the section of RAFT polymerization since iniferter monomers …

… Hypervalent iodine-based radicals and sterically hindered tertiary radicals are considered
only as short- lived intermediates (case 4). However, under some conditions they may be …

… in iniferter systems no exogenous radical initiators are needed; photocleavage of the iniferter
… The ease of generating • CX 3 radicals from hypervalent iodine carboxylates enables their …

… For instance, block copolymers from cationically polymerizable vinyl ethers with vinyl
monomers polymerizable by radical means were prepared by combining iniferter with PROAD …

The mechanisms of most organic reactions are considered to proceed by two-electron
transfer pathways, even though both biology and radical chemistry rely extensively on one-…