Form past till now, green chemistry has been considered as a promising technique for the organic synthesis of materials toward environmental sustainability and economic development. The prominent duties of green chemistry are the enhancement of production efficacy and decrement of waste generation during the operation. In order to implement this process in industries, important green strategies like avoiding waste production, application of catalytic amount of catalyst, reduction of energy consumption and eventually, employment of renewable /bio-degradable substances must be paid attention. The industrial-based application of ionic liquids, deep eutectic solvents and nanofluids have recently been of great interest as eco-friendly, bio-degradable and green materials, which significantly improve the efficiency of green synthesis of organic materials. This paper aims to comprehensively review the breakthrough and cutting-edge methodologies for sustainable and green synthesis of organic materials. Then after, the advantages, performance and the mechanism of action for each technique are explained and the environmental challenges toward their efficient industrial application are discussed in detail.