Affordable and highly efficient photocatalysts for the hydrogen evolution reaction (HER) are desirable to replace expensive bulk noble-metal use. Currently, many renewable energy studies are ongoing, focusing on photocatalytic water splitting to generate hydrogen. Transition-metal oxide-embedded TiO₂ photocatalysts have emerged as superior catalysts for the HER. Herein, we synthesize two different ternary composites consisting of TiO₂-based transition-metal mixed oxides embedded onto graphene oxide (GO) layers which provide superior photocatalytic activity and stability during the HER over conventional expensive catalysts. The Fe₂O₃–TiO₂ and V₂O₅–TiO₂ particles were well anchored onto GO sheets, which prevents the agglomeration and allows one to explore maximum surface active sites. The synergistic interaction within the composite via heterojunction formation and the enhanced photophysical nature of the composite were well characterized. The optimized composites of GO-embedded Fe−Ti mixed oxide composite (g-FTMO) and V−Ti mixed oxide composite (g-VTMO) having metal−metal molar ratio of 2:1 with a 3.5 % (w/v) catalyst loading exhibit HER rates of 398.18 and 373.01 μmol h^–1 under solar radiation. The enhanced photocatalytic activity of optimized g-TMMO_2:1 was attributed to (i) the increased surface area by the incorporation of GO and (ii) the fact that the surface active sites with heterojunctions have lower e^––h⁺ pair recombination and faster electron transfer rates. The results reveal that the prepared composites can be treated as effective photocatalysts during the HER, and the conclusions pave the way for exploration of new similar catalysts for other applications.