Interplay of self-association and solvation in polar liquids
The association constants for formation a 1: 1 complex between 4-phenyl azophenol and tri-
n-butylphosphine oxide were measured in mixtures of n-octane and n-decanol, n-octane
and n-hexanoic acid, and n-octane and 2-ethylhexyl acetamide. The experiments provide
insight into the competition between solvent self-association and solvent–solute interactions
in these systems. The solvation properties of the three polar solvents are quite different from
one another and from polar solvents that do not self-associate. Carboxylic acids form dimers …
n-butylphosphine oxide were measured in mixtures of n-octane and n-decanol, n-octane
and n-hexanoic acid, and n-octane and 2-ethylhexyl acetamide. The experiments provide
insight into the competition between solvent self-association and solvent–solute interactions
in these systems. The solvation properties of the three polar solvents are quite different from
one another and from polar solvents that do not self-associate. Carboxylic acids form dimers …
[引用][C] Interplay of Self-Association and Solvation in Polar Liquids
A Valeria, LC MR, S Hongmei - 2013