Intriguing mechanistic labyrinths in gold (I) catalysis
C Obradors, AM Echavarren - Chemical Communications, 2014 - pubs.rsc.org
C Obradors, AM Echavarren
Chemical Communications, 2014•pubs.rsc.orgMany mechanistically intriguing reactions have been developed in the last decade using
gold (I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed
activation of alkynes and allenes, in which this metal plays a central role by stabilising a
variety of complex cationic intermediates.
gold (I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed
activation of alkynes and allenes, in which this metal plays a central role by stabilising a
variety of complex cationic intermediates.
Many mechanistically intriguing reactions have been developed in the last decade using gold(I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic intermediates.
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