Light‐Harvesting Hybrid Hydrogels: Energy‐Transfer‐Induced Amplified Fluorescence in Noncovalently Assembled Chromophore–Organoclay Composites
Angewandte Chemie International Edition, 2011•infona.pl
The noncovalent self‐assembly of chromophores in an organoclay template results in the
formation of fluorescent hybrid hydrogels and films. These clay–dye hybrids act as novel
supramolecular scaffolds for light‐harvesting as the aminoclay (AC) templates the spatial
organization of donor and acceptor molecules to promote Förster resonant energy transfer
(see picture; CS= coronene salt, PS= perylene salt).
formation of fluorescent hybrid hydrogels and films. These clay–dye hybrids act as novel
supramolecular scaffolds for light‐harvesting as the aminoclay (AC) templates the spatial
organization of donor and acceptor molecules to promote Förster resonant energy transfer
(see picture; CS= coronene salt, PS= perylene salt).
The noncovalent self‐assembly of chromophores in an organoclay template results in the formation of fluorescent hybrid hydrogels and films. These clay–dye hybrids act as novel supramolecular scaffolds for light‐harvesting as the aminoclay (AC) templates the spatial organization of donor and acceptor molecules to promote Förster resonant energy transfer (see picture; CS=coronene salt, PS=perylene salt).
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