Long phosphorescent Ca 2 SnO 4 with minuscule rare earth dopant concentration

T Ishigaki, A Torisaka, K Nomizu, P Madhusudan… - Dalton …, 2013 - pubs.rsc.org
T Ishigaki, A Torisaka, K Nomizu, P Madhusudan, K Uematsu, K Toda, M Sato
Dalton Transactions, 2013pubs.rsc.org
Rare-earth doped Ca2SnO4 phosphors were synthesized using a conventional solid state
reaction method. The red phosphorescence of Eu3+ was observed in this system with
persistence time. In the as-prepared samples, the doped rare earth ions occupied both Ca
and Sn sites in the host lattice. The longest phosphorescent persistence property can be
achieved for the Ca2SnO4 phosphors with a 0.1% Eu dopant. Depending on the doped rare
earth ions, afterglow emissions of various colors were observed.
Rare-earth doped Ca2SnO4 phosphors were synthesized using a conventional solid state reaction method. The red phosphorescence of Eu3+ was observed in this system with persistence time. In the as-prepared samples, the doped rare earth ions occupied both Ca and Sn sites in the host lattice. The longest phosphorescent persistence property can be achieved for the Ca2SnO4 phosphors with a 0.1% Eu dopant. Depending on the doped rare earth ions, afterglow emissions of various colors were observed.
The Royal Society of Chemistry
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