Magnetic-entropy change in Mn1. 1Fe0. 9P0. 7As0. 3–xGex
O Tegus, B Fuquan, W Dagula, L Zhang, E Brück… - Journal of alloys and …, 2005 - Elsevier
Journal of alloys and compounds, 2005•Elsevier
We have studied the magnetic properties and magnetic-entropy changes of Mn1. 1Fe0. 9P0.
7As0. 3–xGex compounds with x= 0, 0.05, 0.1, 0.15 and 0.3. X-ray diffraction (XRD) study
shows all the compounds crystallize in the Fe2P-type structure. Magnetic measurements
show that the Curie temperature increases from 150K for Mn1. 1Fe0. 9P0. 7As0. 3 to 380K
for Mn1. 1Fe0. 9P0. 7Ge0. 3. A field-induced first-order magnetic phase transition is
observed above the Curie temperature for the compounds with x up to 0.15. There exists an …
7As0. 3–xGex compounds with x= 0, 0.05, 0.1, 0.15 and 0.3. X-ray diffraction (XRD) study
shows all the compounds crystallize in the Fe2P-type structure. Magnetic measurements
show that the Curie temperature increases from 150K for Mn1. 1Fe0. 9P0. 7As0. 3 to 380K
for Mn1. 1Fe0. 9P0. 7Ge0. 3. A field-induced first-order magnetic phase transition is
observed above the Curie temperature for the compounds with x up to 0.15. There exists an …
We have studied the magnetic properties and magnetic-entropy changes of Mn1.1Fe0.9P0.7As0.3–xGex compounds with x=0, 0.05, 0.1, 0.15 and 0.3. X-ray diffraction (XRD) study shows all the compounds crystallize in the Fe2P-type structure. Magnetic measurements show that the Curie temperature increases from 150K for Mn1.1Fe0.9P0.7As0.3 to 380K for Mn1.1Fe0.9P0.7Ge0.3. A field-induced first-order magnetic phase transition is observed above the Curie temperature for the compounds with x up to 0.15. There exists an optimal composition in which the first-order phase transition is the sharpest. The optimal composition for this system is x=0.1. The maximal magnetic-entropy change derived from the magnetization data is about 40J/(kg K) for a field change from 0 to 3T.
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