Metal–Organic Framework Luminescence in the Yellow Gap by Codoping of the Homoleptic Imidazolate ∞3[Ba(Im)2] with Divalent Europium
JC Rybak, M Hailmann, PR Matthes… - Journal of the …, 2013 - ACS Publications
The rare case of a metal-triggered broad-band yellow emitter among inorganic–organic
hybrid materials was achieved by in situ codoping of the novel imidazolate metal–organic
framework∞ 3 [Ba (Im) 2] with divalent europium. The emission maximum of this dense
framework is in the center of the yellow gap of primary light-emitting diode phosphors. Up to
20% Eu2+ can be added to replace Ba2+ as connectivity centers without causing
observable phase segregation. High-resolution energy-dispersive X-ray spectroscopy …
hybrid materials was achieved by in situ codoping of the novel imidazolate metal–organic
framework∞ 3 [Ba (Im) 2] with divalent europium. The emission maximum of this dense
framework is in the center of the yellow gap of primary light-emitting diode phosphors. Up to
20% Eu2+ can be added to replace Ba2+ as connectivity centers without causing
observable phase segregation. High-resolution energy-dispersive X-ray spectroscopy …
[引用][C] Metal–Organic Framework Luminescence in the Yellow Gap by Codoping of the Homoleptic Imidazolate∞ 3 [Ba (Im) 2] with Divalent Europium
R Jens-Christoph, H Michael, Z Alexander, N Jörn… - 2013