… of the reaction mechanism for the metal-catalyzed hydrostannation of alkynes, alkenes, and
… Although the mechanistic details of the hydrostannation reactions are not fully understood, a …

… key issues to be addressed in the hydrostannation process. Because the reaction selectivity
… This part is organized by the type of hydrostannation reaction involved (metal-catalyzed tin …

… RhCl(COD)] 2 ; L=PPh 3 ) catalyze hydrostannation of terminal acetylenes (RC≡CH; R=Ph, …
MCl 2 L 2 (M=Ni, Pd, Pt, Co)] are also active for the hydrostannation, but with less selectivity. …

… A direct hydrostannation 7 of the cyclopropene double bond … However, transition metal-catalyzed
hydrostannation of … stereo- and regioselective transition metal-catalyzed hydro-, sila-, …

… In contrast to all other transition-metal-catalyzed hydrostannation reactions documented
in … of established Lewis acid mediated trans hydrostannations nor withstand free-radical …

… metal-catalyzed processes was available and essentially dealt with conjugated reductions of
alkenes. 4a We recently reported the hydrostannation … alkenes in hydrostannation reactions…

… of Bu 3 SnH for transition metal-catalyzed hydrostannations. Our conditions allow the use of
variety of alkynes to undergo transition metal-catalyzed hydrostannations. The use of MoBI 3 …

… Recently, the direct or transition metal catalyzed additions of … Rather surprisingly, however,
the transition metal catalyzed ad… Typically, transition metal catalyzed hydrostannations of …

… For example, in the hydrostannation reaction of 1a, the insertion of Pd(0) into H-Sn bond
takes place first, and then the resulting H-Pd-Sn species undergoes the antiMarkovnikov …

… However, this was discovered serendipitously as a side reaction in Pd-catalyzed hydrostannation
… The transition-metal-catalyzed dehydrogenative coupling of secondary stannanes is a …