Microwave photonic synthetic aperture radar (MWP-SAR) offers a larger signal bandwidth than conventional SAR, and its theoretical resolution can be improved to centimeter level. To achieve same order of magnitude resolution in the azimuth direction, long synthetic aperture is always required, which results in extremely high requirements for the accuracy of imaging procedure. Compared with the conventional SAR imaging algorithms, two major problems should be considered: 1) the scattering characteristics of target might vary from the frequency of signal and the angle of incidence, which seriously affects the coherence of received echo and 2) the imaging of the MWP-SAR system is more sensitive to motion errors and therefore requires higher accuracy of motion compensation processing. To solve the above issues, a high-precision imaging method for MWP-SAR is proposed. First, based on the attribute scattering center (ASC) model, this article analyzes the target scattering characteristics with different frequencies and incident angles. Then, according to the influence of scattering phase on MWP-SAR imaging, an optimal subaperture division algorithm is proposed to guarantee the coherence of each subaperture data and better imaging results. Furthermore, to compensate for the effects of high-order motion errors, this article proposes a motion error estimation algorithm based on subimage registration, where the full-aperture high-order motion errors can be divided into multiple linear components, and the flight trajectory of platform can be accurately reconstructed. Finally, a full-aperture time-domain high-precision imaging method is presented, and the effectiveness of the proposed formation is verified by both simulation and actual airborne MWP-SAR data processing.