Moisture-tolerant frustrated Lewis pair catalyst for hydrogenation of aldehydes and ketones
ACS Catalysis, 2015•ACS Publications
In this paper, we report on the development of a bench-stable borane for frustrated Lewis
pair catalyzed reduction of aldehydes, ketones, and enones. The deliberate fine-tuning of
structural and electronic parameters of Lewis acid component and the choice of Lewis base
provided for the first time, a moisture-tolerant FLP catalyst. Related NMR and DFT studies
underpinned the unique behavior of this FLP catalyst and gave insight into the catalytic
activity of the resulting FLP catalyst.
pair catalyzed reduction of aldehydes, ketones, and enones. The deliberate fine-tuning of
structural and electronic parameters of Lewis acid component and the choice of Lewis base
provided for the first time, a moisture-tolerant FLP catalyst. Related NMR and DFT studies
underpinned the unique behavior of this FLP catalyst and gave insight into the catalytic
activity of the resulting FLP catalyst.
In this paper, we report on the development of a bench-stable borane for frustrated Lewis pair catalyzed reduction of aldehydes, ketones, and enones. The deliberate fine-tuning of structural and electronic parameters of Lewis acid component and the choice of Lewis base provided for the first time, a moisture-tolerant FLP catalyst. Related NMR and DFT studies underpinned the unique behavior of this FLP catalyst and gave insight into the catalytic activity of the resulting FLP catalyst.
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