Molecular and atomic arrays in nano-and mesoporous materials synthesis

GD Stucky, A Monnier, F Schüth, Q Huo… - … Crystals and Liquid …, 1994 - Taylor & Francis
GD Stucky, A Monnier, F Schüth, Q Huo, D Margolese, D Kumar, M Krishnamurty, P Petroff
Molecular Crystals and Liquid Crystals Science and Technology. Section …, 1994Taylor & Francis
… Our interest has been to develop a synthesis model which will explain presently known
experimental data and successfully extend organized molecular arrayfinorganic interface
chemistry to the general synthesis of silicate and non siliceous mesostructure materials. … The
approach that we have taken is to consider the synthesis phase space and the properties of
the lamellar, hexagonal and cubic mesophases in the context of the above description, ie the
interface chemistry of two phase-separated organic and inorganic arrays. In this paper, studies …
Abstract
A model is presented to explain the formation and morphologies of 3-d periodic surfactant-silicate mesostructures. The structures of lamellar, hexagonal tubular and a minimal surface cubic liquid crystal/silicate phase are described.
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