New invariant expressions in chemical kinetics
Entropy, 2020•mdpi.com
This paper presents a review of our original results obtained during the last decade. These
results have been found theoretically for classical mass-action-law models of chemical
kinetics and justified experimentally. In contrast with the traditional invariances, they relate to
a special battery of kinetic experiments, not a single experiment. Two types of invariances
are distinguished and described in detail: thermodynamic invariants, ie, special
combinations of kinetic dependences that yield the equilibrium constants, or simple …
results have been found theoretically for classical mass-action-law models of chemical
kinetics and justified experimentally. In contrast with the traditional invariances, they relate to
a special battery of kinetic experiments, not a single experiment. Two types of invariances
are distinguished and described in detail: thermodynamic invariants, ie, special
combinations of kinetic dependences that yield the equilibrium constants, or simple …
This paper presents a review of our original results obtained during the last decade. These results have been found theoretically for classical mass-action-law models of chemical kinetics and justified experimentally. In contrast with the traditional invariances, they relate to a special battery of kinetic experiments, not a single experiment. Two types of invariances are distinguished and described in detail: thermodynamic invariants, i.e., special combinations of kinetic dependences that yield the equilibrium constants, or simple functions of the equilibrium constants; and “mixed” kinetico-thermodynamic invariances, functions both of equilibrium constants and non-thermodynamic ratios of kinetic coefficients.
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