Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly (hydroxyurethane amide) s
L Maisonneuve, AS More, S Foltran, C Alfos, F Robert… - RSC …, 2014 - pubs.rsc.org
RSC advances, 2014•pubs.rsc.org
Fatty acid-based bis-cyclic 5-membered carbonates containing amide linkages were
prepared from methyl 10-undecenoate. The reaction in bulk of these bio-based carbonates
with a series of di-amines led to poly (hydroxyurethane amide) s with molar masses up to 31
000 g mol− 1. As expected, the so-formed bio-based thermoplastic poly (hydroxyurethane) s
exhibit amorphous to semi-crystalline features with respect to the chemical structure of the
monomers used.
prepared from methyl 10-undecenoate. The reaction in bulk of these bio-based carbonates
with a series of di-amines led to poly (hydroxyurethane amide) s with molar masses up to 31
000 g mol− 1. As expected, the so-formed bio-based thermoplastic poly (hydroxyurethane) s
exhibit amorphous to semi-crystalline features with respect to the chemical structure of the
monomers used.
Fatty acid-based bis-cyclic 5-membered carbonates containing amide linkages were prepared from methyl 10-undecenoate. The reaction in bulk of these bio-based carbonates with a series of di-amines led to poly(hydroxyurethane amide)s with molar masses up to 31 000 g mol−1. As expected, the so-formed bio-based thermoplastic poly(hydroxyurethane)s exhibit amorphous to semi-crystalline features with respect to the chemical structure of the monomers used.
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