Nuclear spin singlet order selection by adiabatically ramped RF fields

AS Kiryutin, AN Pravdivtsev… - The Journal of …, 2016 - ACS Publications
… We describe an NMR method to generate singlet order in spin pairs from longitudinal spin
… for generating and observing long-lived spin states. A singlet order selection (SOS) filter is …

Constant-adiabaticity radiofrequency pulses for generating long-lived singlet spin states in NMR

BA Rodin, KF Sheberstov, AS Kiryutin… - The Journal of …, 2019 - pubs.aip.org
… performance of singlet-state Nuclear Magnetic Resonance (… pairs by applying adiabatically
ramped RF-fields. Test … ramp down the RF-field from ν 1 m a x to zero in an adiabatic fashion. …

Using optimal control methods with constraints to generate singlet states in NMR

BA Rodin, AS Kiryutin, AV Yurkovskaya… - Journal of Magnetic …, 2018 - Elsevier
… by using adiabatically ramped RF-fields. Optimization utilizes … ramped RF-pulses. Since
the simple assumption of monotonously varied pulse envelopes does not guarantee adiabatic

Manipulating Singlet Order with Adiabatic Pulses

AS Kiryutin, BA Rodin, NN Lukzen, AV Yurkovskaya… - 2020 - books.rsc.org
… 1 is the RF-field strength and Î is the nuclear spin operator. Away … By ramping up an RF-field
in an adiabatic way we can … the singlet order has been termed Singlet Order Selection (SOS)…

Multiple-targeting NMR signal selection by optimal control of nuclear spin singlet

X Yang, KR Hu, JX Xin, YX Li, G Yang, DX Wei… - Journal of Magnetic …, 2022 - Elsevier
… The key step in GRAPE is to update the rf fields on the basis of(4) ω rf I iq ( t j ) → ω rf I iq ( t j
) + ε T r { χ + ( t j … It can be used to simultaneously prepare two or more nuclear singlet orders. …

Singlet-filtered NMR spectroscopy

S Mamone, N Rezaei-Ghaleh, F Opazo… - Science …, 2020 - science.org
Nuclear spin singlet states allow the selection of signals from … singlet order from magnetization
(magnetization to singlet), a … Then, a DIPSI2 mixing sequence with an RF field strength of …

Selective filtration of NMR signals arising from weakly-and strongly-coupled spin systems

J Lu, A Jerschow, DE Korenchan - Journal of Magnetic Resonance, 2023 - Elsevier
… editing sequences exploiting nuclear spin interactions in … Kiryutin et al. developed the
Singlet Order Selection (SOS) … using adiabatically-ramped RF fields, known as the Adiabatic-…

Polychromatic excitation of delocalized long-lived proton spin states in aliphatic chains

A Sonnefeld, G Bodenhausen, K Sheberstov - Physical Review Letters, 2022 - APS
… Ivanov, Robust conversion of singlet spin order in coupled spin-1=2 pairs by adiabatically
Vieth, and KL Ivanov, Nuclear spin singlet order selection by adiabatically ramped rf fields, J. …

Generating and sustaining long-lived spin states in 15N,15N′-azobenzene

KF Sheberstov, HM Vieth, H Zimmermann, BA Rodin… - Scientific reports, 2019 - nature.com
… efficient spin order conversion, we make use of adiabatic NMR … These methods are the
singlet order selection filter 49,50 and … of the adiabatic RF field increases or decreases. All these …

Long-lived Singlet State: From NMR Quantum Information Perspectives

TS Mahesh, D Khurana - 2020 - books.rsc.org
… NMR spectroscopy relies on the fact that nuclear spin ensembles in … The discovery of
long-lived nuclear spin order further … designed improved adiabatically ramped RF-fields for robust …