On the rate equation of nucleation and the concept of active sites in electrodeposition
J Wijenberg, WH Mulder, M Sluyters-Rehbach… - … chemistry and interfacial …, 1988 - Elsevier
On the basis of the assumption that on a homogeneous surface area a probability 0< P (E,
c)< 1 for nucleation can be defined which increases with the monomer concentration c and
is also dependent on the potential E, it is shown both by a schematic computer simulation
and by an approximate analytical derivation that necessarily the number of nuclei has to
attain a limiting value for long times, without having to resort to the existence of active sites. It
follows that this limiting number arises from a concurrence between the probability of …
c)< 1 for nucleation can be defined which increases with the monomer concentration c and
is also dependent on the potential E, it is shown both by a schematic computer simulation
and by an approximate analytical derivation that necessarily the number of nuclei has to
attain a limiting value for long times, without having to resort to the existence of active sites. It
follows that this limiting number arises from a concurrence between the probability of …
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