Peripheral Ligand Effect on the Photophysical Property of Octahedral Iridium Complex: o-Aryl Substitution on the Phenyl Units of Homoleptic IrIII(C∧C)3 Complexes (C∧C = 1-Phenyl-3 …
To evaluate the efficacy of ortho-arylation in the second coordination sphere of octahedral
iridium complex, a series of homoleptic N-heterocyclic carbene (NHC)-based Ir (C∧ CR) 3-
type complexes were designed and prepared by introducing various substituents (R= H, Me,
Ph, MePh, and diMePh) at the ortho-position of the aryl unit of the orthometalated phenyl
group. In solution, an unnoticeable increase of emission quantum yields was observed
within the variation of the ortho-substituent of the sterically demanding side-branch, a …
iridium complex, a series of homoleptic N-heterocyclic carbene (NHC)-based Ir (C∧ CR) 3-
type complexes were designed and prepared by introducing various substituents (R= H, Me,
Ph, MePh, and diMePh) at the ortho-position of the aryl unit of the orthometalated phenyl
group. In solution, an unnoticeable increase of emission quantum yields was observed
within the variation of the ortho-substituent of the sterically demanding side-branch, a …
To evaluate the efficacy of ortho-arylation in the second coordination sphere of octahedral iridium complex, a series of homoleptic N-heterocyclic carbene (NHC)-based Ir(C∧CR)3-type complexes were designed and prepared by introducing various substituents (R = H, Me, Ph, MePh, and diMePh) at the ortho-position of the aryl unit of the orthometalated phenyl group. In solution, an unnoticeable increase of emission quantum yields was observed within the variation of the ortho-substituent of the sterically demanding side-branch, a diMePh– group, showing the radiative quantum yield of mer-Ir(C∧CdiMePh)3 (ΦPL = 1.9%), being higher than that of the unsubstituted carbene-based mer-Ir(C∧CH)3 (ΦPL = 1.2%), due to a considerable difference in the nonradiative decay rate (knr = 65.40 × 105 s–1 for mer-Ir(C∧CdiMePh)3 vs knr = 141.1 × 105 s–1 for mer-Ir(C∧CH)3). Such a difference is attributed to the reduction of nonradiative pathway via the 3MLCT → 3MC transition by the widening gap between triplet emissive states and 3MC state, and a rigidity increase in structure by steric hindrance of bulky aryl substituent. In contrast, significant increase of emission quantum yield was observed in the films cast by spin coating, and fac-/mer-Ir(C∧CdiMePh)3 (ΦPL = 60.1/49.1%) were the most efficient ones among NHC–Ir(III) complexes, compatible with the assumption that the secondary coordination effect, i.e. a peripheral constraint, was put into action. As the substituent R increases in size on going from H, Me, Ph, MePh, to diMePh, notable structural changes in the periphery are evident, while an increase of emission quantum yields is also seen. Such a peripheral difference was under scrutiny first with X-ray structural studies, and its manifestation in photophysics was investigated along with quantum calculations that finally addressed the peripheral effect being maximized at R = diMePh. In the application of PhOLED, the mer-Ir(C∧CdiMePh)3-doped multilayer device showed highly enhanced efficiency with an external quantum efficiency (EQE) of up to 8.1%, compared to that of the mer-Ir(C∧CH)3-based device (1.2%), indicating the multiple positive effects of bulky aryl substitution of Ir(III) dopant. A deep-blue CIE chromaticity diagram (0.16, 0.09) was achieved from the device using mer-Ir(C∧CdiMePh)3 as a dopant.
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