Quantifying lithium loss in amorphous silicon thin-film anodes via titration-gas chromatography

W Bao, C Fang, D Cheng, Y Zhang, B Lu… - Cell Reports Physical …, 2021 - cell.com
Silicon with a high theoretical capacity (3,579 mAh/g) is a promising anode candidate for
lithium-ion batteries. However, commercialization is still impeded by low Coulombic
efficiency, caused by solid electrolyte interphase (SEI) formation and trapped lithium (Li)-
silicon (Si) alloy during repeated volume change. Quantifying capacity losses from each
factor is crucial to formulate rational design strategies for further improvement. In this work,
titration-gas chromatography and cryogenic transmission electron microscopy are applied to …

[PDF][PDF] Quantifying lithium loss in amorphous silicon thin-film anodes via titration-gas

W Bao, C Fang, D Cheng - Cell Reports, 2021 - scholar.archive.org
Silicon with a high theoretical capacity (3,579 mAh/g) is a promising anode candidate for
lithium-ion batteries. However, commercialization is still impeded by low Coulombic
efficiency, caused by solid electrolyte interphase (SEI) formation and trapped lithium (Li)-
silicon (Si) alloy during repeated volume change. Quantifying capacity losses from each
factor is crucial to formulate rational design strategies for further improvement. In this work,
titration-gas chromatography and cryogenic transmission electron microscopy are applied to …
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