Raman scattering efficiency of graphene

P Klar, E Lidorikis, A Eckmann, IA Verzhbitskiy… - Physical Review B …, 2013 - APS
Physical Review B—Condensed Matter and Materials Physics, 2013APS
We determine the Raman scattering efficiency of the G and 2 D peaks in graphene. Three
substrates are used: silicon covered with 300 or 90 nm oxide, and calcium fluoride (CaF 2).
On Si/SiO x, the areas of the G and 2 D peak show a strong dependence on the substrate
due to interference effects, while on CaF 2 no significant dependence is detected.
Unintentional doping is reduced by placing graphene on CaF 2. We determine the Raman
scattering efficiency by comparison with the 322 cm− 1 peak area of CaF 2. At 2.41 eV, the …
We determine the Raman scattering efficiency of the and peaks in graphene. Three substrates are used: silicon covered with 300 or 90 nm oxide, and calcium fluoride (CaF). On Si/SiO, the areas of the and peak show a strong dependence on the substrate due to interference effects, while on CaF no significant dependence is detected. Unintentional doping is reduced by placing graphene on CaF. We determine the Raman scattering efficiency by comparison with the 322 cm peak area of CaF. At 2.41 eV, the Raman efficiency of the peak is mSr, and changes with the excitation energy to the power of 4. The Raman efficiency is at least one order of magnitude higher than that of the peak, with a different excitation energy dependence.
American Physical Society
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